Ok. Go with Blender if you going for 3d. for the most part you can't go wrong. What you can go wrong is learning how it work. It not an easy tool.
If that model is from the game it falls against copyright law and you CAN NOT USE IT! If the model was created from scratch in a "likeness of the character" meaning not an exact copy of their character and you get permission from its creator then its perfectly legal to use.